首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   18584篇
  免费   2474篇
  国内免费   1686篇
电工技术   2201篇
综合类   1657篇
化学工业   1376篇
金属工艺   1374篇
机械仪表   1474篇
建筑科学   2973篇
矿业工程   1207篇
能源动力   1567篇
轻工业   215篇
水利工程   848篇
石油天然气   931篇
武器工业   262篇
无线电   1356篇
一般工业技术   2816篇
冶金工业   661篇
原子能技术   231篇
自动化技术   1595篇
  2024年   39篇
  2023年   410篇
  2022年   713篇
  2021年   890篇
  2020年   864篇
  2019年   849篇
  2018年   617篇
  2017年   789篇
  2016年   780篇
  2015年   834篇
  2014年   1266篇
  2013年   1273篇
  2012年   1413篇
  2011年   1517篇
  2010年   1112篇
  2009年   1144篇
  2008年   982篇
  2007年   1102篇
  2006年   1046篇
  2005年   816篇
  2004年   684篇
  2003年   644篇
  2002年   550篇
  2001年   411篇
  2000年   338篇
  1999年   286篇
  1998年   238篇
  1997年   212篇
  1996年   150篇
  1995年   142篇
  1994年   115篇
  1993年   91篇
  1992年   78篇
  1991年   56篇
  1990年   46篇
  1989年   44篇
  1988年   38篇
  1987年   17篇
  1986年   15篇
  1985年   21篇
  1984年   15篇
  1983年   16篇
  1982年   5篇
  1980年   8篇
  1979年   14篇
  1963年   4篇
  1961年   5篇
  1960年   6篇
  1959年   7篇
  1955年   7篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
61.
In collaborative crowdsourcing communities for open innovation, users generate and submit ideas as idea co‐creators. Firms then select and implement valuable ideas for new product development. Despite the popularity and success of these open innovation communities, relatively little is known about the factors that determine the implementation of the user‐generated ideas. Based on research on individual creativity, we propose a conceptual model integrating users' previous experience, idea presentation characteristics and feedback valence to explain the likelihood of idea implementation. We validate our research model with a panel data analysis of 43 550 ideas submitted by 16 360 users in the MIUI new product development community hosted by Xiaomi, a large electronics manufacturing company in China. We find an inverted U‐shaped relationship between users' past successful experience and idea implementation. Furthermore, the length of ideas is positively associated with the likelihood of idea implementation. There is also an inverted U‐shaped relationship between supporting evidence and idea implementation. Finally, we demonstrate the negative effect of positive feedback and the positive effect of negative feedback on idea implementation. These findings offer rich insights to understand the phenomenon of open innovation better. Theoretical and practical implications are discussed.  相似文献   
62.
Dynamic indirect tension experiments were performed on zirconium diboride-silicon carbide (ZrB2−20%SiC) ceramic. Flattened Brazilian disc specimens of ZrB2−20%SiC were prepared to conduct dynamic tensile tests using the modified Split Hopkinson pressure bar system. The tensile experiments were completed at the range of loading rates from 7.53 to 74.71 GP s−1. The tensile experimental results revealed that the zirconium diboride-silicon carbide ceramic composite is rate-sensitive in terms of the tensile strength and failure mode. The dynamic tensile strength increases linearly with the loading rate and changes from 195 MPa at 7.53 GP s−1 to 654 MPa at 74.71 GP s−1. Moreover, the dynamic tensile strength decreases with the increase in critical fracture time, which conforms to Tuler and Butcher's fracture criterion. In dynamic experiments, a high-speed camera was used to examine the tensile failure process, and fragments were collected to analyze the dynamic tensile failure mechanism. The tensile fracture mode of ZrB2−20%SiC obviously showed the sensitivity of the loading rate. The fragment size of ZrB2−20%SiC ceramic decreased but the quantity of fragments increased as the loading rate increased.  相似文献   
63.
In this study highly oriented, rutile phase one dimensional Titania nanorod array (TiO2 NRA) modified by gadolinium doping were synthesized on the conductive glass substrate (FTO) by the hydrothermal method. The effect of Gd doping on the photoelectrochemical performance of TiO2 NRA was investigated. Crystal phase, structural, morphological and composition characteristics of these synthesized photoelectrodes were analyzed by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), energy dispersive spectroscopy (EDS), and atomic force microscopy (AFM). FE-SEM images clearly show that some of the Gd dopant is uniformly distributed on the surface of TiO2 NRA in the form Gadolinia (Gd2O3) microsphere. These gadolinia microsphere play an important role in reducing the surface recombination of electron and hole supported by photoluminescence's studies. Linear sweep voltammetry results show that Gd doping results in a two-fold increase in photocurrent density as compared to pristine TiO2 NRA. UV–visible spectra, and Mott-Schotty measurements show that Gd doping shift the flat-band potential of TiO2 NRA more toward negative potential that results in effective charge separation and transportation in the Gd doped TiO2 NRA (Gd@TiO2 NRA). Applied biased photon to current efficiency (ABPE) equation was used to find solar to hydrogen efficiency (STH). Gd@TiO2 NRA show optimum conversion efficiency of ~0.64% at 0.03 V vs Ag/AgCl, while pristine TiO2 NRA display ~0.33% at −0.21 V vs Ag/AgCl.  相似文献   
64.
张中岭  卢彦山 《中州煤炭》2020,(10):144-149
同一个多功能集控器件长期使用后,其不同故障程度对应有不同故障现象,为了加快现场技术管理人员对提升机疑难故障的有效排除进度,着重分析了制动油泵停转的控制通道,根据提升机启动操作中制动油泵停转后的排查处理结果,圈定了故障范围为变频控制器件。制动油泵在提升机启动操作中停转的不确定性,查找故障时整机电控系统处于非故障状态,接近更换变频主控板D6时启动提升机操作中制动油泵软性停转次数有所增多、启动中无发生制动油泵停转的全程提升未见异常,上述因素使制动油泵软性停转成为疑难杂症。故障现象恶化为每次操作至制动手把推向松闸位置制动油泵均停转,用梯形图确定D6故障是症结所在。对D6的自身故障精确定位功能且在变频控制柜人机界面RJ2显示故障信息认识不足,导致故障长时存在。此副井提升机有关人员应做到:对故障反映到位、深刻了解器件性能特征、透析有关动作过程后方可采取针对性措施、确定故障元件、最终排除故障。可恢复性的轻故障发生后必须采取相应措施,避免故障扩大导致停机延误提升。将变频就绪与故障的实时信息显示于司控台面,弥补了技改缺陷。  相似文献   
65.
This article analytically investigates the temperature influence on the performance of laterally constrained dielectric elastomer actuators. The effects of both temperature and stretches on the permittivity are taken into consideration. The governing equations of state are established by modeling the actuator as a thermodynamic system of three degrees of freedom. Various failure modes, including electromechanical instability, electric breakdown, loss of tension, and tensile rupture are considered to restrict the operation state and to determine the region of allowable state. Numerical calculations are performed to depict the variations of some important physical quantities with generalized coordinates and to gain insight on the influence of temperature on the critical curves of failures. It is shown that the temperature has obvious effects on the operation state and the allowable region. The present results can be used for designing and optimizing an actuator, and the present approach can be extended to other kinds of dielectric elastomer actuators with complex geometries.  相似文献   
66.
Developing highly active, stable and sustainable electrocatalysts for overall water splitting is of great importance to generate renewable H2 for fuel cells. Herein, we report the synthesis of electrocatalytically active, nickel foam-supported, spherical core-shell Fe-poly(tetraphenylporphyrin)/Ni-poly(tetraphenylporphyrin) microparticles (FeTPP@NiTPP/NF). We also show that FeTPP@NiTPP/NF exhibits efficient bifunctional electrocatalytic properties toward both the oxygen evolution reaction (OER) and the hydrogen evolution reaction (HER). Electrochemical tests in KOH solution (1 M) reveal that FeTPP@NiTPP/NF electrocatalyzes the OER with 100 mA cm−2 at an overpotential of 302 mV and the HER with 10 mA cm−2 at an overpotential of 170 mV. Notably also, its catalytic performance for OER is better than that of RuO2, the benchmark OER catalyst. Although its catalytic activity for HER is slightly lower than that of Pt/C (the benchmark HER electrocatalyst), it shows greater stability than the latter during the reaction. The material also exhibits electrocatalytic activity for overall water splitting reaction at a current density of 10 mA cm−2 with a cell voltage of 1.58 V, along with a good recovery property. Additionally, the work demonstrates a new synthetic strategy to an efficient, noble metal-free-coordinated covalent organic framework (COF)-based, bifunctional electrocatalyst for water splitting.  相似文献   
67.
Fabrication of an electrocatalyst with remarkable electrocatalytic activity for both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is important for the production of hydrogen energy. In this study, Ni–Co–W alloy urchin-like nanostructures were fabricated by binder-free and cost-effective electrochemical deposition method at different applied current densities and HER and OER electrocatalytic activity was studied. The results of this study showed that the microstructure and morphology are strongly influenced by the electrochemical deposition parameters and the best electrocatalytic properties are obtained at the electrode created at the 20 mA.cm−2applied current density. The optimum electrode requires −66 mV and 264 mV, respectively, for OER and HER reactions for delivering the 10 mA cm−2 current density. The optimum electrode also showed negligible potential change after 10 h electrolysis at 100 mA cm−2, which means remarkable electrocatalytic stability. In addition, when this electrode used as a for full water splitting, it required only 1.58 V to create a current density of 10 mA cm−2. Such excellent electrocatalytic activity and stability can be related to the high electrochemical active surface area, being binder-free, high intrinsic electrocatalytic activity and hydrophilicity. This study introduces a simple and cost-effective method for fabricating of effective electrodes with high electrocatalytic activity.  相似文献   
68.
介绍了压包机的工作原理、控制方式、逻辑联锁、液压系统以及压包机常见的故障和维修保养等。  相似文献   
69.
The occurrence of perioperative heart failure will affect the quality of medical services and threaten the safety of patients. Existing methods depend on the judgment of doctors, the results are affected by many factors such as doctors’ knowledge and experience. The accuracy is difficult to guarantee and has a serious lag. In this paper, a mixture prediction model is proposed for perioperative adverse events of heart failure, which combined with the advantages of the Deep Pyramid Convolutional Neural Networks (DPCNN) and Extreme Gradient Boosting (XGBOOST). The DPCNN was used to automatically extract features from patient’s diagnostic texts, and the text features were integrated with the preoperative examination and intraoperative monitoring values of patients, then the XGBOOST algorithm was used to construct the prediction model of heart failure. An experimental comparison was conducted on the model based on the data of patients with heart failure in southwest hospital from 2014 to 2018. The results showed that the DPCNN-XGBOOST model improved the predictive sensitivity of the model by 3% and 31% compared with the text-based DPCNN Model and the numeric-based XGBOOST Model.  相似文献   
70.
《Ceramics International》2020,46(9):13125-13132
It is of great significance to develop highly active and cost-effective electrocatalysts for the oxygen evolution reaction and hydrogen evolution reaction in alkaline solution. Herein, we report an interface engineering strategy to fabricate 3D hierarchical CuCo2O4@CuCo2S4 heterostructure catalysts with efficient synergistic effects for water splitting. Owing to the special nano-architectures with abundant active interfaces, the as-prepared CuCo2O4@CuCo2S4 catalysts exhibit superior electrochemical activity and prominent electrochemical stability, with a small overpotential of 240 and 101 mV for oxygen and hydrogen evolution reactions to deliver a current density of 10 mA cm−2, respectively. Remarkably, the CuCo2O4@CuCo2S4 materials directly applied as both anode and cathode electrode demonstrate excellent water splitting performance, achieving 10 mA cm−2 at a low cell voltage of only 1.53 V, outperforming the integrated state-of-the-art RuO2||Pt/C couple (1.56 V). Moreover, density functional theory calculations suggest that the excellent overall water splitting property of CuCo2O4@CuCo2S4 is attributed to a large amount of hierarchical hetero-interfaces, giving rise to effective adsorption and cleavage of H2O molecules on the catalyst surface. This work represents a general strategy to exploit efficient and stable hybrid electrocatalysts for renewable energy applications by rational catalyst interface engineering.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号